Simultaneous Spectrofluorometric Determination of Piroxicam and Pyridoxine Using Generalized Rank Annihilation Method

Simultaneous spectrofluorometric determination of piroxicam and pyridoxine using generalized rank annihilation method.

The application of generalized rank annihilation method (GRAM) to the analysis of fluorescence excitation-emission matrices of mixtures of piroxicam and pyridoxine is described. The input of GRAM consists of two bilinear data matrices, i.e. one for unknown and one for the calibration sample. The excitation wavelength range was from 290 to 340 nm and the emission was recorded from 370 to 560 nm....

Generalized Rank Annihilation Method . 111 : Practical Implementation

Derivation of the generalized rank annihilation method (GRAM)

Introduction The generalized rank annihilation method (GRAM) is a method for curve resolution and calibration that requires only a single calibration sample to obtain the socalled second-order advantage, i.e., it can determine the analyte of interest in the presence of unsuspected interferences [1]. GRAM is only one of many competing methods that can be applied to this particular data set-up. H...

multiwavelength pectrophotometric determination of stability constants of 4-(2– thiazolylazo) resorcinol (tar) with la3+, y3+ and th4+ in organic-water mixed solvents by chemometrics method & simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares calibration method

تشکیل کمپلکس های tarبا یون های لانتانیم, ایتریم و توریم در دمای 25 درجه، قدرت یونی ثابت 0.1 مولار و در ph ثابت در مخلوط حلال های اتانول – آب و استونیتریل – آب با استفاده از روش های اسپکتروفوتومتری مورد بحث و بررسی قرار گرفت. داده های اسپکتروفوتومتری با استفاده از نرم افزار squad پردازش شدند تا ثابت های تشکیل کمپلکس اندیکاتور – فلز را محاسبه کند. نتایج نشان می دهد که درصد حلال آلی در مخلوط حلال ...

Simultaneous kinetic-spectrofluorometric determination of levodopa and carbidopa using partial least-squares regression.

A simple and sensitive methodology for the simultaneous determination of levodopa and carbidopa in pharmaceutical samples is described. The method combines the advantages of fluorescence with partial least-squares (PLS) analysis, and requires no previous separation steps. The developed method is based on the oxidation of levodopa and carbidopa by cerium(IV) in a sulfuric acid medium and monitor...